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The necessity of pop over to this website the brand new inter-BrnNTE Br⋯O relationships try after that supported by comparing the brand new phosphorescence from crystalline BrnNTE with this of your dispersed particles in the poly(methyl methacrylate) (PMMA, Mw ∼996 kDa; 2 wt% doping). The brand new rigid polymer matrix is anticipated so you can constrain the fresh unit activity at the room temperature however, disturb inter-BrnNTE Br⋯O halogen ties. The newest phosphorescence spectra of Br1NTE stayed identical either in environment (Fig. 2), proving the triplet decay in the Br1NTE is basically intrinsic so you can the fresh monomeric molecule.

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The speed constants kobs and kTT (purple to own rac-BINAP and you will bluish to own Roentgen-BINAP) are deduced regarding the research match Eq. B The brand new literary works mentioned decay duration of tangerine-red-colored reduced-issue RTP particles (to own details of per amount, excite see A lot more Dining table step 3 and you can A lot more Fig. 20)39,40,41,42,43,forty-two,forty-five,46. Spectral short term growth of your own PL range to possess (c) rac-BINAP and you may (d) R-BINAP inside unmarried crystal counted from the type decrease go out with a home thickness from 200 μs.